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Effect of carbon deposition over carbonaceous catalysts on CH

Yongfa ZHANG, Meng ZHANG, Guojie ZHANG, Huirong ZHANG

《化学科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 481-485 doi: 10.1007/s11705-010-0523-8

摘要： An investigation was made using a continuous fixed bed reactor to understand the influence of carbon deposition obtained under different conditions on CH -CO reforming. Thermogravimetry (TG) and X-ray diffraction (XRD) were employed to study the characteristics of carbon deposition. It was found that the carbonaceous catalyst is an efficient catalyst in methane decomposition and CH -CO reforming. The trend of methane decomposition at lower temperatures is similar to that at higher temperatures. The methane conversion is high during the initial of stage of the reaction, and then decays to a relatively fixed value after about 30 min. With temperature increase, the methane decomposition rate increases quickly. The reaction temperature has significant influence on methane decomposition, whereas the carbon deposition does not affect methane decomposition significantly. Different types of carbon deposition were formed at different methane decomposition reaction temperatures. The carbon deposition Type I generated at 900°C has a minor effect on CH -CO reforming and it easily reacts with carbon dioxide, but the carbon deposition Type II generated at 1000°C and 1100°C clearly inhibits CH -CO reforming and it is difficult to react with carbon dioxide. The results of XRD showed that some graphite structures were found in carbon deposition Type II.

关键词： carbon deposition     carbonaceous catalyst     CH4-CO2 reforming    

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ECOLOGICAL EFFECTS OF NITROGEN DEPOSITION ON URBAN FORESTS: AN OVERVIEW

《农业科学与工程前沿（英文）》 2022年 第9卷 第3期   页码 445-456 doi: 10.15302/J-FASE-2021429

摘要：

● Patterns and effects of N deposition on urban forests are reviewed.

关键词： biodiversity     carbon sequestration     nitrogen deposition     nutrient imbalance     soil acidification     urban forest    

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Large-scale industrial manufacturing of carbon nanotubes in a continuous inclined mobile-bed rotatingreactor via the catalytic chemical vapor deposition process

Sophie L. Pirard, Sigrid Douven, Jean-Paul Pirard

《化学科学与工程前沿（英文）》 2017年 第11卷 第2期   页码 280-289 doi: 10.1007/s11705-017-1635-1

摘要： This article reports the different steps of the design, development and validation of a process for continuous production of carbon nanotubes (CNTs) via catalytic chemical vapor deposition from the laboratory scale to the industrial production. This process is based on a continuous inclined mobile-bed rotating reactor and very active catalysts using methane or ethylene as carbon source. The importance of modeling taking into account the hydrodynamic, physicochemical and physical phenomena that occur during CNT production in the process analysis is emphasized. The impact of this invention on the environment and human health is taken into consideration too.

关键词： carbon nanotubes     catalytic chemical vapor deposition     inclined rotating reactor     industrial process     scaling-up    

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The role of ions in plasma catalytic carbon nanotube growth: A review

Erik C. Neyts

《化学科学与工程前沿（英文）》 2015年 第9卷 第2期   页码 154-162 doi: 10.1007/s11705-015-1515-5

摘要： While it is well-known that the plasma-enhanced catalytic chemical vapor deposition (PECVD) of carbon nanotubes (CNTs) offers a number of advantages over thermal CVD, the influence of the various individual contributing factors is not well understood. Especially the role of ions is unclear, since ions in plasmas are generally associated with sputtering rather than with growing a material. Even so, various studies have demonstrated the beneficial effects of ion bombardment during the growth of CNTs. This review looks at the role of the ions in plasma-enhanced CNT growth as deduced from both experimental and simulation studies. Specific attention is paid to the beneficial effects of ion bombardment. Based on the available literature, it can be concluded that ions can be either beneficial or detrimental for carbon nanotube growth, depending on the exact conditions and the control over the growth process.

关键词： plasma-enhanced chemical vapor deposition (PECVD)     carbon nanotube (CNT)     ion bombardment     defect healing    

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Direct synthesis of carbon nanotubes on fly ash particles to produce carbon nanotubes/fly ash composites

Fangxian LI, Cheng ZHOU, Pengfei YANG, Beihan WANG, Jie HU, Jiangxiong WEI, Qijun YU

《结构与土木工程前沿（英文）》 2019年 第13卷 第6期   页码 1405-1414 doi: 10.1007/s11709-019-0564-0

摘要： Fly ash was used as catalytic support for carbon nanotubes (CNTs) growth by chemical vapor deposition (CVD) due to having ideal compositions (SiO , Al O , and Fe O ). In this paper, CNTs were synthesized on Ni catalyst/fly ash substrate using CVD method. The influence of parameters (e.g., reaction temperature and gas flow rate) on the carbon yield and structure of the resulting CNTs was on the carbon yield and structure of the resulting CNTs was investigated by thermo-gravimetric analyses, Scanning electron microscopy, and Raman spectroscopy analysis. The results indicated that the growth temperature controlling had a significant effect on the diameter of CNTs. And the proper acetylene and hydrogen flow rate would decrease in defect density and increase in yield of as-grown CNTs on fly ash. Finally, the amorphous carbon on the surface of as-grown CNTs were removed by heating in air. Experimental results showed that the hydrophobic of the annealed CNTs was weak due to introducing functional groups to the surface of CNTs.

关键词： carbon nanotubes     fly ash     chemical vapor deposition     parameters     purification    

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Improvement in growth yield of single-walled carbon nanotubes with narrow chirality distribution by pulse

Bin Xu, Toshiro Kaneko, Toshiaki Kato

《化学科学与工程前沿（英文）》 2019年 第13卷 第3期   页码 485-492 doi: 10.1007/s11705-019-1831-2

摘要： A pulse plasma chemical vapor deposition (CVD) technique was developed for improving the growth yield of single-walled carbon nanotubes (SWNTs) with a narrow chirality distribution. The growth yield of the SWNTs could be improved by repetitive short duration pulse plasma CVD, while maintaining the initial narrow chirality distribution. Detailed growth dynamics is discussed based on a systematic investigation by changing the pulse parameters. The growth of SWNTs with a narrow chirality distribution could be controlled by the difference in the nucleation time required using catalysts comprising relatively small or large particles as the key factor. The nucleation can be controlled by adjusting the pulse on/off time ratio and the total processing time.

关键词： single-walled carbon nanotubes     chirality-controlled synthesis     pulse plasma chemical vapor deposition    

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Scaling up of cluster beam deposition technology for catalysis application

《化学科学与工程前沿（英文）》 2021年 第15卷 第6期   页码 1360-1379 doi: 10.1007/s11705-021-2101-7

摘要： Many research works have demonstrated that the combination of atomically precise cluster deposition and theoretical calculations is able to address fundamental aspects of size-effects, cluster-support interactions, and reaction mechanisms of cluster materials. Although the wet chemistry method has been widely used to synthesize nanoparticles, the gas-phase synthesis and size-selected strategy was the only method to prepare supported metal clusters with precise numbers of atoms for a long time. However, the low throughput of the physical synthesis method has severely constrained its wider adoption for catalysis applications. In this review, we introduce the latest progress on three types of cluster source which have the most promising potential for scale-up, including sputtering gas aggregation source, pulsed microplasma cluster source, and matrix assembly cluster source. While the sputtering gas aggregation source is leading ahead with a production rate of ~20 mg·h–1, the pulsed microplasma source has the smallest physical dimensions which makes it possible to compact multiple such devices into a small volume for multiplied production rate. The matrix assembly source has the shortest development history, but already show an impressive deposition rate of ~10 mg·h–1. At the end of the review, the possible routes for further throughput scale-up are envisaged.

关键词： nanoparticle     cluster     cluster beam deposition     magnetron sputtering     heterogeneous catalysis    

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Deposition of copper nanoparticles on multiwalled carbon nanotubes modified with poly (acrylic acid)

Li SHENG,Shuhang HUANG,Minghao SUI,Lingdian ZHANG,Lei SHE,Yong CHEN

《环境科学与工程前沿（英文）》 2015年 第9卷 第4期   页码 625-633 doi: 10.1007/s11783-014-0711-8

摘要： A novel hybrid material, Cu-PAA/MWCNTs (copper nanoparticles deposited multiwalled carbon nanotubes with poly (acrylic acid) as dispersant, was prepared and expected to obtain a more effective and well-dispersed disinfection material for water treatment. X-ray energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), the X-ray fluorescence (XRF), X-ray photoelectron spectra (XPS), Fourier transform infrared spectra (FT-IR), Raman spectroscopy, and thermal gravimetric analyzer (TGA) were used to characterize the Cu-PAA/MWCNTs. ( ) was employed as the target bacteria. The cell viability determination and fluorescence imaging results demonstrated that Cu-PAA/MWCNTs possessed strong antimicrobial ability on . The deposited Cu was suggested to play an important role in the antimicrobial action of Cu-PAA/MWCNTs.

关键词： multiwalled carbon nanotubes     copper nanoparticles     antimicrobial activity     Escherichia coli (E. coil)    

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Influence mechanism of dynamic and static liquid bridge forces on particle deposition behaviors in solar

Xueqing LIU, Xiaodong ZHAO, Luyi LU, Jianlan LI

《能源前沿（英文）》 2021年 第15卷 第2期   页码 499-512 doi: 10.1007/s11708-021-0742-3

摘要： Solar energy is one of the most promising forms of renewable energy for solving the energy crisis and environmental problems. Dust deposition on photovoltaic mirrors has a serious negative impact on the photoelectric conversion efficiency of solar power stations. In this paper, the influence mechanism of the dynamic and static liquid bridge forces on particle deposition behaviors on solar photovoltaic mirrors is investigated. In addition, the expression and physical meaning of the particle critical separation velocity are proposed. The research results show that the static liquid bridge force can be the primary deposition force causing dust particles to adhere to photovoltaic mirrors. However, the dynamic liquid bridge force can act as a resistance force for the particle motion process and even make dust particles roll along and finally stay on the mirror. The contact force is the primary separation force that causes dust particles to flow away from the mirror. Whether dust particles adhere to the mirror depends on the relative size of the deposition and separating forces. The particle critical separation velocity describes the relative size of the collision-rebound effect and mirror adhesion effect and is expressed in Eq. (16). These research findings can provide theoretical guidance for mirror cleaning methods in the operation process of photovoltaic mirrors.

关键词： dust deposition     discrete element method (DEM)     photovoltaic mirrors     solar energy    

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Fault simulation of boiler heating surface ash deposition in a power plant system

Weiwei ZHANG, Huisheng ZHANG, Ming SU

《能源前沿（英文）》 2011年 第5卷 第4期   页码 435-443 doi: 10.1007/s11708-011-0162-x

摘要： The simulation model of a power generation system was developed based on EASY5 simulation platform. The performances of the power plant under the conditions of the furnace slagging and ash deposition of the heating surfaces in the boiler were simulated. The results show that the simulation model can reasonably reflect the characteristics of the power plant when each component is under fault conditions. Through fault simulation, the change of the performance parameters can be obtained, which can be used in fault diagnosis system as the diagnosis criterion for expert system.

关键词： boiler     slagging     ash deposition     fault simulation    

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Influence of phosphate on deposition and detachment of TiO

Zhan Wang, Chongyang Shen, Yichun Du, Yulong Zhang, Baoguo Li

《环境科学与工程前沿（英文）》 2019年 第13卷 第5期 doi: 10.1007/s11783-019-1163-y

摘要： We examined influence of phosphate on transport of TiO2 NPs in soil. Deposition was reduced at higher pH and by adsorption of phosphate in soil. Release was more for NPs initially deposited at higher pH. Release was more for NPs initially deposited in the presence of phosphate. Surface roughness and charge heterogeneity play a role in the deposition/ release. The widespread use of TiO2 nanoparticles (NPs) makes inevitable their release into the soil. Phosphate is also widespread within soil, and is likely copresent with TiO2 NPs. However, the influence of phosphate on deposition/release— and thereby on transport— of TiO2 NPs in soil is yet to be elucidated. In this study we conducted saturated column experiments to systematically examine the transport of TiO2 NPs in soil amended with phosphate at different ionic strengths (ISs) (1, 10, 100 mmol/L NaCl) and pHs (4 and 9). Results show that the deposition of TiO2 NPs decreased with decreasing IS, increasing pH, and when soil absorbed phosphate. These observations are qualitatively in agreement with Derjaguin-Landau-Verwey-Overbeek (DLVO) interaction energy calculations, because the repulsive energy barrier is larger and secondary minimum depth is smaller at a lower IS, higher pH, and in the presence of phosphate. Accordingly, both primary- and secondary-minimum deposition were inhibited. Interestingly, although the deposition was less at higher pH and in the presence of phosphate, the subsequent spontaneous detachment and detachment by reduction of solution IS in these cases were greater. In addition, the presence of phosphate in the solution can cause a small quantity of attached TiO2 NPs to detach, even without perturbations of physical and chemical conditions. Our study was the first to investigate the influence of phosphate on detachment of TiO2 NPs and the results have important implication for accurate prediction of fate and transport of TiO2 NPs in subsurface environments.

关键词： Phosphate     TiO2 nanoparticles     Transport     Soil     Deposition     Detachment    

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Thermodynamic analysis of steam reforming of glycerol for hydrogen production at atmospheric pressure

Ammaru Ismaila, Xueli Chen, Xin Gao, Xiaolei Fan

《化学科学与工程前沿（英文）》 2021年 第15卷 第1期   页码 60-71 doi: 10.1007/s11705-020-1975-0

摘要： Thermodynamic chemical equilibrium analysis of steam reforming of glycerol (SRG) for selective hydrogen production was performed based on the Gibbs free energy minimisation method. The ideal SRG reaction (C H O +3H O→3CO +7H ) and a comprehensive set of side reactions during SRG are considered for the formation of a wide range of products. Specifically, this work focused on the analysis of formation of H CO , CO and CH in the gas phase and determination of the carbon free region in SRG under the conditions at atmospheric pressure, 600€K–1100€K and 1.013 × 10 –1.013 × 10 Pa with the steam-to-glycerol feed ratios (SGFR) of 1:5–10. The reaction conditions which favoured SRG for H production with minimum coke formation were identifies as: atmospheric pressure, temperatures of 900€K–1050€K and SGFR of 10:1. The influence of using the inert carrier gas (i.e., N ) in SRG was studied as well at atmospheric pressure. Although the presence of N in the stream decreased the partial pressure of reactants, it was beneficial to improve the equilibrium yield of H . Under both conditions of SRG (with/without inert gas), the CH production is minimised, and carbon formation was thermodynamically unfavoured at steam rich conditions of SGFR>5:1.

关键词： steam reforming of glycerol     H2     N2     carbon deposition     thermodynamic analysis     Gibbs free energy minimisation    

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RESEARCH PROGRESS ON THE IMPACT OF NITROGEN DEPOSITION ON GLOBAL GRASSLANDS

《农业科学与工程前沿（英文）》 2022年 第9卷 第3期   页码 425-444 doi: 10.15302/J-FASE-2022457

摘要：

● Grasslands in many regions of the world have been impacted by atmospheric nitrogen deposition.

关键词： Acidification     biomass production     critical load     eutrophication     species composition     species richness    

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Lagrangian simulation of deposition of CO gas-solid sudden expansion flow

HUANG Dongping, DING Guoliang, QUACK Hans

《能源前沿（英文）》 2008年 第2卷 第2期   页码 216-221 doi: 10.1007/s11708-008-0032-3

摘要： Freezing and blockage resulting from the deposition of solid CO formed because of sudden expansion of the downstream pipe during the release of CO through safety valves, will endanger the protected equipment. To overcome this problem, the characteristics of the CO gas-solid sudden expansion flow are studied by using the disperse Lagrangian model. A comparison of the calculated deposition of the solid CO with the experimental results shows that they are in reasonable agreement. The simulation results show that the size of the solid CO formed should not be in the range of 0.04–0.07 mm ( number 3.2–9.8). This can be achieved by using an appropriate flow cross section of the safety valve.

关键词： comparison     gas-solid     downstream     blockage     Lagrangian    

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Effect of soil crust on evaporation and dew deposition in Mu Us sandy land, China

SUN Yongliang, LI Xiaoyan, XU Heye, YANG Zhipeng, TANG Jia, ZHANG Xiaoying

《环境科学与工程前沿（英文）》 2008年 第2卷 第4期   页码 480-486 doi: 10.1007/s11783-008-0034-8

摘要： The development of soil crust on sandy land may affect the surface hydrological process. This paper investigates the process of evaporation and dew deposition influenced by different soil surface types which were dominated by sand, primitive biotic crust, and advanced biotic crust, respectively, in the south fringe of Mu Us sandy land in Northwest China from July to September of 2006. The experimental results indicate that the advanced biotic crust could increase evaporation and dew deposition compared to the primitive biotic crust and bare sand although the differences between them were not significant. The average evaporation from advanced biotic crust, primitive biotic crust and sand was 6.8, 6.6, and 6.5 mm/d, respectively, and water content is around 16.2 % in the condition of initially identical soil. The average dew amount on advanced biotic crust was 0.116 mm/d with extreme 0.05 and 0.24 mm/d. The average values on primitive biotic crust and sand were 0.105 and 0.101 mm/d, respectively, with extreme 0.04 and 0.21 mm/d for both treatments. Also, the dew deposition on advanced biotic crust seemed stable and might rest for a longer time than that on primitive biotic crust and sand. The results suggest that the advanced biotic crust possibly facilitates evaporation and dew deposition. Therefore, the development of biotic crust may potentially enhance the hydrological circulation in the upper sand layer in sandy land.
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标题 作者 时间 类型 操作

Effect of carbon deposition over carbonaceous catalysts on CH

Yongfa ZHANG, Meng ZHANG, Guojie ZHANG, Huirong ZHANG

期刊论文

ECOLOGICAL EFFECTS OF NITROGEN DEPOSITION ON URBAN FORESTS: AN OVERVIEW

期刊论文

Large-scale industrial manufacturing of carbon nanotubes in a continuous inclined mobile-bed rotatingreactor via the catalytic chemical vapor deposition process

Sophie L. Pirard, Sigrid Douven, Jean-Paul Pirard

期刊论文

The role of ions in plasma catalytic carbon nanotube growth: A review

Erik C. Neyts

期刊论文

Direct synthesis of carbon nanotubes on fly ash particles to produce carbon nanotubes/fly ash composites

Fangxian LI, Cheng ZHOU, Pengfei YANG, Beihan WANG, Jie HU, Jiangxiong WEI, Qijun YU

期刊论文

Improvement in growth yield of single-walled carbon nanotubes with narrow chirality distribution by pulse

Bin Xu, Toshiro Kaneko, Toshiaki Kato

期刊论文

Scaling up of cluster beam deposition technology for catalysis application

期刊论文

Deposition of copper nanoparticles on multiwalled carbon nanotubes modified with poly (acrylic acid)

Li SHENG,Shuhang HUANG,Minghao SUI,Lingdian ZHANG,Lei SHE,Yong CHEN

期刊论文

Influence mechanism of dynamic and static liquid bridge forces on particle deposition behaviors in solar

Xueqing LIU, Xiaodong ZHAO, Luyi LU, Jianlan LI

期刊论文

Fault simulation of boiler heating surface ash deposition in a power plant system

Weiwei ZHANG, Huisheng ZHANG, Ming SU

期刊论文

Influence of phosphate on deposition and detachment of TiO

Zhan Wang, Chongyang Shen, Yichun Du, Yulong Zhang, Baoguo Li

期刊论文

Thermodynamic analysis of steam reforming of glycerol for hydrogen production at atmospheric pressure

Ammaru Ismaila, Xueli Chen, Xin Gao, Xiaolei Fan

期刊论文

RESEARCH PROGRESS ON THE IMPACT OF NITROGEN DEPOSITION ON GLOBAL GRASSLANDS

期刊论文

Lagrangian simulation of deposition of CO gas-solid sudden expansion flow

HUANG Dongping, DING Guoliang, QUACK Hans

期刊论文

Effect of soil crust on evaporation and dew deposition in Mu Us sandy land, China

SUN Yongliang, LI Xiaoyan, XU Heye, YANG Zhipeng, TANG Jia, ZHANG Xiaoying

期刊论文